Mix the paprika, chili powder, cumin, thyme, and salt together in a large bowl. Add the shrimp to the spices and toss to coat evenly. Set aside.

Melt the butter over medium heat in a 12-inch skillet. Add the garlic and cook, stirring with a wooden spoon, for one minute. Add the shrimp and continue cooking over medium heat, stirring frequently, until the shrimp are done, 3-4 minutes. Add the Worcestershire sauce, lemon juice and wine and cook until 2 minutes more. Garnish with green onions and serve with lemon wedges.